The Ising model - Introduction
The Ising model (in its one-dimensional version) was proposed by Ernst Ising in his PhD thesis in 1925 as a tool to describe the thermodynamic properties of magnetic systems from a microscopic point of view. Ising found (as we will shortly see) that in the case he considered the system does not exhibit any phase transition for , and he incorrectly concluded that the whole model was not useful to describe such systems. However, this model has been later studied again and in different configurations and many important properties have been discovered; historically Ising model has been one of the most (if not the most itself) heavily studied model in statistical mechanics and it is often used as a testing ground when new theories or methods are developed. Another extremely important characteristic of the Ising model, that also justifies the effort we will make in order to study it, is that it does not only apply to magnetic systems: as we will see many other systems can be shown to be equivalent to an appropriately defined Ising model.
The -dimensional Ising model is defined as follows: consider a -dimensional lattice with sites, each labelled by the index ; in general the lattice is supposed to be hypercubic, but this is not necessary: in two dimensions, for example, we can consider triangular or "honeycomb" lattices, while in three dimensions we can have body-centered or face-centered cubic lattices. What distinguishes one lattice from another is its coordination number, defined as the number of the nearest neighbours of a site. In the case of hypercubic lattices it can be easily seen (case by case) that , where is the dimensionality of the system. The degrees of freedom of the model are discrete variables defined on each site that can only assume the values and ; therefore, the number of the possible configurations of the system is .
In the original purpose of the Ising model the lattice represents the atomic lattice of a metal and the variables are the spins of the atoms, or rather their component along the vertical axis; therefore, corresponds to a spin pointing upwards while downwards, and the study of this model should determine if and how all these spins can align so that the system can have a spontaneous net magnetization. However, since the Ising model can be used to describe completely different systems this interpretation is not the only possible one; even though, since this model has always been associated to magnets (but also for historical reasons) we will in the following continue to use a terminology proper only to magnetic systems.
Visually, for various dimensions the Ising model can be represented as follows:
The usefulness of the Ising model (but in general of lattice theories) goes much further that what can now be imagined (considering also the fact that this model can be used to describe systems different from magnetic ones). Lattice theories are in fact widely used in many areas of physics: just as an example, apart from "easily imaginable" applications of the Ising model in solid state physics, also quantum relativistic theories can be formulated in terms of lattices. QCD, for example, widely uses four-dimensional lattice models (with Minkowski spatio-temporal metric, of course) to describe quantum phenomena. We therefore see that also models with "strange" dimensionality (i.e. greater than ) can be actually useful.
In order for this model to be interesting, the degrees of freedom must not be independent: we therefore assume that the spins interact with each other with exchange interactions that couple in general an arbitrary number of spins, and also with an external field that can change from site to site. Therefore, the most general form of the Hamiltonian of the Ising model for a given spin configuration is:
For the sake of simplicity, from now on we will always neglect interactions that couple more than two spins, and we will also consider the field as constant over the system.
Now, what about the existence of the thermodynamic limit for the Ising model? It has been shown that in general the thermodynamic limit exists if the two-spin interaction satisfies:
- Examples of such systems are fluids (see Ising model and fluids), binary alloys (see Ising model and binary alloys) and neural networks (see Ising model and neural networks).
- The number of possible lattices is predicted by group theory, and amazingly all these mathematically possible lattices are found in nature.
- Note that from quantum mechanics we know that in general the spin of an atom is proportional to a given fraction of : we are "ignoring" the magnitude of the spin, "reabsorbing" it in the definition of the coupling constants.
- This is not really true: as we will see in Ising model and the ideal gas, we can learn something interesting also in the non-interacting case.
- In the study of this situation, including the one in which there is no external field, we will use the method of sources: this consists in keeping always the term containing in the Hamiltonian, and at the end of the calculations (i.e. after the thermodynamic limit) set to any desired constant value, including zero.